This study maps the intellectual structure and thematic evolution of sustainable entrepreneurship and green innovation research. Applying a bibliometric and integrative review to 270 Scopus-indexed articles (2010–2026), findings reveal rapid interdisciplinary expansion (22.28% annual growth). Thematic mapping identifies climate change and entrepreneurship increasingly integrating artificial intelligence as motor themes, while sustainable development provides the foundational framework. Green innovation emerges as a fast-growing frontier alongside the circular economy as a specialized niche. Co-citation analyses expose a dual intellectual foundation anchored in corporate sustainability theory and robust PLS-SEM methodology. Acknowledging limitations regarding Scopus exclusivity and citation-window effects, this review urges future research to enforce strict construct separation between entrepreneurship and innovation outcomes. By advocating for longitudinal designs to clarify causal ordering, this synthesis offers a consolidated roadmap for advancing theoretical development.